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Depends on what you meant by your quesiton.
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If you meant <em>Can a pawn, going backwards, take another piece</em>, the answer is no, a pawn can never move backwards.
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If you meant <em>Can a pawn, going forward, take another piece that just moved backwards</em>, the answer is yes, a pawn can always take a piece which is on one of the squares immediately diagonally forward of the pawn.
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- Sam